## Abstract ^13^C and ^15^N NMR chemical shifts were measured for __N__^1^‐alkyl‐__N__^2^‐arylthioureas. The absence of decoalescence of the __N__^1^‐alkyl group carbon signals down to 190 K, the europium‐induced chemical shifts and the molecular mechanics calculations indicate that the preferred c
NMR studies in the heterocyclic series XXIV—1H, 13C and 15N study of 15N labelled indazoles
✍ Scribed by Alain Fruchier; Valdo Pellegrin; Rémy Schimpf; José Elguero
- Publisher
- John Wiley and Sons
- Year
- 1982
- Tongue
- English
- Weight
- 352 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
The ^15^N chemical shifts and ^1^H^15^N and ^13^C^15^N coupling constants of nine monolabelled indazoles were measured and assigned. The experimental values are discussed in terms of the indazolic and iso‐indazolic structures, and compared with literature data for other related heterocycles. All the results are consistent with an N‐1(H) tautomeric structure for indazole in DMSO‐d~6~.
📜 SIMILAR VOLUMES
## Abstract Three __N__‐substituted pyrazoles and three __N__‐substituted indazoles [1‐(4‐nitrophenyl)‐3,5‐dimethylpyrazole (1), 1‐(2,4‐dinitrophenyl)‐3,5‐dimethylpyrazole (2), 1‐tosyl‐pyrazole (3), 1‐__p__‐chlorobenzoylindazole (4), 1‐tosylinda‐zole (5) and 2‐(2‐hydroxy‐2‐phenylethyl)‐indazole (6)
## Abstract Novel 2‐acetylamino‐4‐acetyl‐5‐aryl(heteryl)‐1,3,4‐thiadiazolines, 2‐acetylamino‐5‐aryl(heteryl)‐1,3,4‐thiadiazoles, and some of their salts were prepared and studied by multinuclear ^1^H, ^13^C, ^15^N, ^19^F and 2D NMR spectroscopy. The acetylation of thiosemicarbazones is accompanied
## Abstract One‐ and two‐dimensional NMR spectra of Tröger's base, (±)‐2,8‐dimethyl‐6__H__,12__H__‐5,11‐methanodibenzo[__b,f__][1,5]diazocine labelled on one of the nitrogen atoms, have been used to determine the chemical shifts, coupling constants, and Δ^13^C(^15^N) isotope shifts. Copyright © 200
## Abstract ^13^C and ^15^N NMR spectra of eight substituted 1,2,4‐triazines were measured and assigned. The assignments of the ^13^C NMR spectra were based on the substituent chemical shifts and ^__n__^__J__(C,H) coupling constants. ^15^N NMR chemical shifts generally showing well separated ranges
C and 15 N NMR data are reported for nine azoloazines. From the results obtained it is found that the 15 N chemical shifts are particularly well placed to provide reliable data on both the structures of the compounds studied and on their potential to undergo valence and prototropic tautomerism. Of p