NMR Spectroscopy of Polymers

✍ Scribed by Prof. Dr. Koichi Hatada, Prof. Dr. Tatsuki Kitayama (auth.)

• Publisher: Springer-Verlag Berlin Heidelberg
• Year: 2004
• Tongue: English
• Leaves: 230
• Series: Springer Laboratory
• Edition: 1
• Category: Library

✦ Synopsis

NMR Spectroscopy of Polymers places emphasis on the practical use of NMR spectroscopy in polymer chemistry rather than the theoretical treatments. Based on the authors' extensive experimental experience, topics covered include (1) experimental problems such as preparation of sample solution, selection of solvent, internal standard and tube, and contaminants in sample solution, (2) accuracy and precision of NMR measurements required in the analysis of polymer structure such as tacticity, copolymer composition and chain end structures, (3) volume magnetic susceptibility by NMR, (4) stereochemistry of polymer chains, chemical composition and comonomer sequence distribution in copolymers, and end groups and irregular linkages, (5) on-line coupled size exclusion chromatography(SEC) and NMR spectroscopy(SEC/NMR) in which an NMR spectrometer is set in the SEC system as a detector.

✦ Table of Contents

Front Matter....Pages I-XII
Introduction to NMR Spectroscopy....Pages 1-42
Measurement of Spectrum with High-Quality Including Quantitative Analysis....Pages 43-71
Stereochemistry of Polymers....Pages 73-93
Copolymer....Pages 95-121
NMR for the Study of Polymerization Reactions....Pages 123-142
Two-dimensional NMR Spectroscopy....Pages 143-168
NMR Relaxation....Pages 169-197
On-line SEC/NMR Analysis of Polymers....Pages 199-208
Back Matter....Pages 209-222

✦ Subjects

Polymer Sciences; Condensed Matter Physics; Analytical Chemistry; Physical Chemistry