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NMR spectroscopic properties of heptakis(2,6-di-O-pentyl)-β-cyclodextrin: Two-dimensional NMR spectra of a key intermediate in preparing chiral stationary phases for enantioselective capillary gas chromatography

✍ Scribed by Wolfram Meier-Augenstein; Barend V. Burger; Hendrik S. C. Spies


Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
413 KB
Volume
29
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

The ^1^H and ^13^C NMR spectra of heptakis(2,6‐di‐O‐pentyl)‐β‐cyclodextrin in deuteriochloroform have been fully and unambiguously assigned. Several methods, including homo‐ and heteronuclear spin decoupling, two‐dimensional homo‐ and hetero‐nuclear correlation NMR spectroscopy, spectral simulation and the measurement of relaxation times were used for chemical shift assignments.