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NMR spectra of the porphyrins. 30—Calibration and application of a ring current model for cobalt(III) meso-tetraphenylporphyrin (CoTPP) complexes

✍ Scribed by Raymond J. Abraham; Craig J. Medforth


Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
606 KB
Volume
25
Category
Article
ISSN
0749-1581

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The NMR spectra of the porphyrins. 36—Ri
✍ Raymond J. Abraham; Craig J. Medforth 📂 Article 📅 1988 🏛 John Wiley and Sons 🌐 English ⚖ 912 KB

The change in ring current of octaethylporphyrin, meso-tetraphenylporphyrin and phthalocyanine cobalt(II1) complexes with axial amine ligands was studied using a double dipole network model. The porphyrin ring current was found to be highest in octaethylporphyrin but decreased by 5% in meso-tetraphe

The NMR spectra of the porphyrins 16—zin
✍ Raymond J. Abraham; Geoffrey R. Bedford; David McNeillie; Brian Wright 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 English ⚖ 777 KB

## Abstract The facile preparation of zinc(II) __meso__‐tetraphenylporphyrin (Zn TPP) and derivatives from substituted benzaldehydes and pyrrole, combined with the calculation of ring current shifts in these molecules, provides a useful series of selective diamagnetic shift reagents. The porphyrin‐