NMR Shielding Constants in PH 3 , Absolute Shielding Scale, and the Nuclear Magnetic Moment of 31 P
✍ Scribed by Lantto, Perttu; Jackowski, Karol; Makulski, Włodzimierz; Olejniczak, Małgorzata; Jaszuński, Michał
- Book ID
- 121087352
- Publisher
- American Chemical Society
- Year
- 2011
- Tongue
- English
- Weight
- 782 KB
- Volume
- 115
- Category
- Article
- ISSN
- 1089-5639
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The magnetic shielding constant of the nucleus of the dimethylphosphate anion is calculated by an eb initio method for different values of the torsion angles about the PO ester bond and different orientations of the methyl groups. The results obtained tend to show that both types of conformational p
Rcccivcd 14 Scptcmbcr 1970 Anisotropies 01 the 13C shielding constant @UC) for CIinI and Cll+!X arc obtained from 'k SMi1 studies of these molcculcs in the ncmatic solvents. The results arc compnrcd with the Lhcorctkal vnlues obtained by the molccuklr orhitnl cnlculxtions using thz current theory. T