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NMR relaxation study of the phase transitions and relaxation mechanisms of the alums MCr(SO4)2·12H2O (M=Rb and Cs) single crystals

✍ Scribed by Ae Ran Lim; Younkee Paik; Kye-Young Lim

Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
583 KB
Volume
184
Category
Article
ISSN
0022-4596

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NMR relaxation study of the local enviro
NMR relaxation study of the local environments and phase transitions of CsCr(SO4)2·12H2O and CsAl(SO4)2·12H2O single crystals
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## Abstract Low‐temperature, polarized, single‐crystal Raman spectra of the β‐alums CsM(SO~4~)~2~. 12H~2~O (M = Mo or Ru) and their deuterated analogues were recorded between 275 and 1200 cm^−1^. The internal modes of sulphate and [M(OH~2~)~6~]^3+^ and the external modes of water coordinated to the