NMR of59Co in K3Co(CN)6 (II)
β Scribed by Lourens, J. A. J. ;Reynhardt, E. C.
- Book ID
- 105367713
- Publisher
- John Wiley and Sons
- Year
- 1972
- Tongue
- English
- Weight
- 523 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0031-8965
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π SIMILAR VOLUMES
Co triple-quantum (3Q) MAS and single-pulse MAS NMR spectra of K 3 Co(CN) 6 have been obtained at 14.1 T and used in a comparison of these methods for determination of small chemical shift anisotropies for spin I = 7/2 nuclei. From the 3QMAS NMR spectrum a spinning sideband manifold in the isotropic
## Abstract Cobaltβ59 NMR measurements were made on an aqueous solution of K~3~[Co(CN)~6~] with pressure as the main variable. We determined the effect of temperature and pressure (up to 5 kbar) on (i) the cobaltβ59 chemical shift, (ii) the carbonβcobaltβ59 isotope shift, (iii) the cobaltβ59βcarbon