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NMR investigation of phase transitions in solid CH4CD4 mixtures

✍ Scribed by F. Lostak; K.O. Prins; N.J. Trappeniers


Publisher
Elsevier Science
Year
1986
Weight
142 KB
Volume
139-140
Category
Article
ISSN
0378-4363

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✦ Synopsis


311th publication of the Van der Waals Fund)

The pressure-temperature phase diagram of solid CH4-CD 4 mixtures up to high pressure is determined by means of the observation of the anomaly in the proton spin-lattice relaxation time. Special attention is given to the transition between the solid phases II and III and to the disappearance of this transition in mixtures with a CD 4 concentration below 15%.


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Octupolar glass structure in a solid Ch4
✍ F. De Luca; B. Maraviglia 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 244 KB

Evidence for the existence of an orientational glass structure in a CH4---Kr mixture with 35% Rr was obtained with MlR measurements. Our results sdd an "octupolar ghss" to the already known "quadrupolar glass" of ortho-para hydrogen.