NMR investigation of phase transitions in solid CH4CD4 mixtures
✍ Scribed by F. Lostak; K.O. Prins; N.J. Trappeniers
- Publisher
- Elsevier Science
- Year
- 1986
- Weight
- 142 KB
- Volume
- 139-140
- Category
- Article
- ISSN
- 0378-4363
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✦ Synopsis
311th publication of the Van der Waals Fund)
The pressure-temperature phase diagram of solid CH4-CD 4 mixtures up to high pressure is determined by means of the observation of the anomaly in the proton spin-lattice relaxation time. Special attention is given to the transition between the solid phases II and III and to the disappearance of this transition in mixtures with a CD 4 concentration below 15%.
📜 SIMILAR VOLUMES
Evidence for the existence of an orientational glass structure in a CH4---Kr mixture with 35% Rr was obtained with MlR measurements. Our results sdd an "octupolar ghss" to the already known "quadrupolar glass" of ortho-para hydrogen.