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NMR in chemistry: A multinuclear introduction

✍ Scribed by Purchase, Rupert


Book ID
122370758
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
145 KB
Volume
25
Category
Article
ISSN
0278-6915

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## Abstract By means of ^27^Al, ^1^H, ^17^O and ^13^C NMR spectroscopy the structure of the methylaluminoxane (MAO) cocatalyst of Kaminsky‐Sinn catalysts was investigated. We have found that the ^27^Al NMR resonance line of MAO is extremely broad at room temperature (Ξ΄ β‰ˆ 60, Δω~1/2~ 50 Β± 10 kHz). A