NMR identification of left-handed polyproline type II helices
β Scribed by Sik Lok Lam; Victor L. Hsu
- Book ID
- 101719197
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2003
- Tongue
- English
- Weight
- 250 KB
- Volume
- 69
- Category
- Article
- ISSN
- 0006-3525
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The influence of steric effects on the helical geometry and the interconversion of type II to type I polyproline in water was examined by the synthesis and analysis of proline dimers and hexamers containing up to three (2S,5R)-5-tert-butylproline residues. In the dimers, the bulky 5-tert-butyl subst