NMR-Experiments on Acetals. XVI. Low Temperature Experiments and Conformational Data on 4-Substituted CIS-1,3-Dioxadecalanes
β Scribed by G. Swaelens; M. Anteunis
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 433 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0037-9646
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π SIMILAR VOLUMES
## Abstract Thermodynamic parameters for the __cisβtrans__ equilibrium of 2, 4βdisubstituted 1, 3βdioxolanes were evaluated using gaschromatographic data. The equilibrium is always close to 60:40 (cis:trans), and only very slightly dependent on the nature of the substituents. The __t. butyl__ group
## Abstract Quantitative conformational data are reported for the title compounds (Table I), as obtained from an extensive ^1^HβNMR study at several temperatures. Identification of the Meβ5 signals (axial or equatorial) at T < T~C~ could be achieved by spectral comparison with the corresponding ana