✦ LIBER ✦

NMR evidence for two ammonia rotational hindering potentials in solid Ca(NH3)6

✍ Scribed by K.B. Rawlings; R.F. Marzke; W.S. Glaunsinger

Book ID: 103019178
Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 442 KB
Volume: 95
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)85078-7

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✦ Synopsis

Protorr spin -I;txricc rchsarion times in Ca(Ntl~)s h;lve been mcasurrd betwcn 10 xtd 125 I<. Three distinct T, minima hxc brrn ohscrvcd and xc attributed IO NH3 diffusion and to NH3 rotriting in two different hinderin_r potentink. The resulrs ?;utr~est that there is an apprechblc diffcrcncc in molecular structure betwcm NH3 and ND3 in this compound.