## Abstract Several __C__^9^โcarbamoyl derivatives of quinine have been prepared and compared as chiral solvating agents in NMR enantiodiscrimination experiments of amino acid derivatives. The origin of the enantiodiscrimination phenomena was identified by NMR conformational analysis of the chiral
NMR enantiodiscrimination by pentafluorophenylcarbamoyl derivatives of quinine: C10 versus C9derivatization
โ Scribed by Gloria Uccello-Barretta; Letizia Vanni; Margherita Giulia Berni; Federica Balzano
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 419 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0899-0042
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๐ SIMILAR VOLUMES
The 1 H and 13 C NMR spectra of a set of structurally related tricyclic quinones consisting of 4,4-dimethylanthracene-1,9,10(4H)-trione (1), 4,4,6,7-tetramethylanthracene-1,9,10(4H)-trione (2) and the regioisomers 4,4,5-(3), 4,4,6-(4), 4,4,7-(5) and 4,4,8trimethylanthracene-1,9,10(4H)-trione (6) wer
## Abstract Carbonโ13, carbonโ13 oneโbound and longโrange coupling constants are determined for anthracene and 9,10โdihydroanthracene labelled in the 9,10โpositions, and for thiophthalic anhydride and phthalimide, labelled in both carbonyl groups. Relative signs are determined by the SDL method. Si