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NMR coupling of 13C and 19F with 14N in nitro compounds

✍ Scribed by Michael D. Coburn; Carlyle B. Storm; Donald W. Moore; Thomas G. Archibald

Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
426 KB
Volume
28
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The ^13^C and ^14^N NMR spectra of a variety of highly nitrated aliphatic, aromatic and heterocyclic compounds were obtained. The proton decoupled ^13^C peaks of the nitro‐substituted carbons in most of these compounds were split into the multiplets expected for coupling with spin 1 nuclei with negligible quadrupolar broadening. In addition, the ^19^F spectra of some fluoronitroaliphatic compounds showed that the ^19^F signals were also split into the expected multiplets from coupling with the ^14^N of the nitro groups.

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