NMR chemical shifts as criteria of the conformation of the nitrogen atom in piperidines
β Scribed by M.J.T. Robinson
- Book ID
- 108385197
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 251 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The shielding of an axial proton by an adjacent, axial lone pair on nitrogen was first No. 25
Recently new indications for the existence of preferred, distinct orientations of the carbonyl group in 3-12-membered cycloalkanones was found by the present author'. The orientation of the carbonyl group seemed to change in an irregular vay within the series, indicating a preferred orientation ror
## Abstract ^13^Cβnmr chemical shifts of backbone carbonyl and sideβchain Ξ²βcarbons in polypeptides provide structural information. Recent utilization of substituent effects on ^13^Cβnmr chemical shifts (principally Ξ³βeffects) has permitted the rationalization of their sequence and conformation dep