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N.M.R. and X-ray evidence for the structure of 2,5-dithio, 1-phenyl, 1-thiophosphorus (V) cyclopentane

✍ Scribed by J. D. Lee; G. W. Goodacre; S. C. Peake; M. Fild; R. Schmutzler


Publisher
Springer
Year
1970
Tongue
English
Weight
282 KB
Volume
57
Category
Article
ISSN
0028-1042

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Reaction of j?-D-allopyranose with acetic anhydride (7.5 mol)-sodium acetate at room temperature and chromatography of the products gave the known' crystalline /Spyranose penta-acetate (5, 36%), together with the hitherto unknown /Spyranose 1,3,4,6 (1, 21%) and 1,2,3,6-tetra-acetate (2, 12%).