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NMR and X-ray analysis of 25,27-dimethoxythiacalix[4]arene: unique infinite channels in the solid state

✍ Scribed by Pavel Lhoták; Lukáš Kaplánek; Ivan Stibor; Jan Lang; Hana Dvořáková; Richard Hrabal; Jan Sýkora

Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 152 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)01696-8

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✦ Synopsis

The conformational behaviour of 25,27-dimethoxythiacalix[4]arene was studied using NMR techniques and X-ray analysis. The title compound prefers a cone conformation in solution, while in the solid state it adopts a unique 1,2-alternate conformation thus creating a novel type of molecular channel held together by p-p interactions.

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