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NMR and Molecular Mechanics Studies on Configurational Isomerism and Conformational Equilibrium of Chiral Cyclohexenones

✍ Scribed by L. A. Kutulya; N. S. Pivnenko; A. S. Petrenko; V. V. Vashchenko; J. W. Goodby

Book ID
110291297
Publisher
SP MAIK Nauka/Interperiodica
Year
2001
Tongue
English
Weight
691 KB
Volume
42
Category
Article
ISSN
0022-4766

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✍ Robert Glaser πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 484 KB

## Abstract The NMR parameters of (βˆ’)‐scopolamine free base in CDCl~3~ determined by Sarazin __et al.__ were used to reevaluate some of the stereochemical conclusions recently reported by the authors. Similarly to the case with the protonated salt, the major contributor to the fast exchange limit t