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NMR and infrared spectroscopic studies of the self-association of tert-butyl and tert-pentyl hydroperoxides

✍ Scribed by O. P. Yablonskii; V. F. Bystrov; A. N. Vinogradov; V. A. Belyaev; V. N. Zhavoronkov; N. M. Pashchenko; I. A. Maizlakh

Book ID: 112363379
Publisher: Springer
Year: 1972
Tongue: English
Weight: 299 KB
Volume: 6
Category: Article
ISSN: 0040-5760
DOI: 10.1007/bf00525907

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## Abstract tert‐Butylsulfinyl chloride (**1**) reacts smoothly with tert‐butyl hydroperoxide (**2**) in the presence of pyridine to afford a variety of products including pyridinium tert‐butylsulfonate, tert‐butyl tert‐butylthiolsulfonate, tert‐butanol and tert‐butylsulfonyl chloride. The mechanis