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NMR and conformational studies of new 5-phenylpyrrole-carboxamide derivatives

✍ Scribed by Luisa C. López-Cara; M. José Pineda de las Infantas; M. Dora Carrión; M. Encarnación Camacho; Miguel A. Gallo; Antonio Espinosa; Antonio Entrena

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
245 KB
Volume
47
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The ^1^H and ^13^C NMR resonances of 22 5‐(5‐substituted‐2‐nitrophenyl)‐1__H__‐pyrrole‐2‐carboxamides, 22 5‐(5‐substituted‐2‐aminophenyl)‐1__H__‐pyrrole‐2‐carboxamides, and 9 5‐phenyl‐1__H__‐pyrrole‐2‐carboxamides were assigned completely using the concerted application of one‐ and two‐dimensional experiments (DEPT, gs‐HMQC and gs‐HMBC). NOE studies and conformational analysis confirm the preferred conformations of such compounds. Copyright © 2009 John Wiley & Sons, Ltd.

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