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Nitroxide-Mediated Radical Polymerization from CdSe Nanoparticles

✍ Scribed by Sill, Kevin; Emrick, Todd


Book ID
121089321
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
211 KB
Volume
16
Category
Article
ISSN
0897-4756

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## Abstract Nitroxide‐mediated polymerizations of styrene in microemulsion have been carried out at 125 °C using the cationic surfactant tetradecyltrimethylammonium bromide and the nitroxides 2,2,6,6‐tetramethylpiperidinyl‐1‐oxy (TEMPO) and __N__‐__tert__‐butyl‐__N__‐[1‐diethylphosphono‐(2,2‐dimeth

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## Abstract Compartmentalization and nitroxide partitioning in NMP in dispersed systems have been investigated by modeling and simulations. Compartmentalization comprises the segregation effect on termination and the confined space effect on deactivation. Under certain conditions, it is possible to