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Nitroxide-Mediated Polymerization: The Pivotal Role of the k d Value of the Initiating Alkoxyamine and the Importance of the Experimental Conditions

✍ Scribed by Chauvin, Florence; Dufils, Pierre-Emmanuel; Gigmes, Didier; Guillaneuf, Yohann; Marque, Sylvain R. A.; Tordo, Paul; Bertin, Denis


Book ID
121236013
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
256 KB
Volume
39
Category
Article
ISSN
0024-9297

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Nitroxide-Mediated Polymerization of Met
✍ Yohann Guillaneuf; Didier Gigmes; Sylvain R. A. Marque; Paul Tordo; Denis Bertin πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 194 KB

## Abstract **Summary:** The nitroxide‐mediated polymerization (NMP) of MMA initiated with a new crowded SG1‐based alkoxyamine was performed. Contrary to the results expected after a kinetic analysis (Fischer's diagram), the polymerization of MMA at 45 °C with SG1 showed only partial control and li