Nitroxide-Controlled Free-Radical Copolymerization of Vinyl and Divinyl Monomers. 2. Gelation
β Scribed by Ide, Nobuhiro; Fukuda, Takeshi
- Book ID
- 126807515
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 89 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0024-9297
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The TobitaβHamielec kinetic model of the crosslink density distribution is further elaborated and extended to incorporate divinyl loop formation. Divinyl loop formation, primary and secondary cyclization, and their effects on the elastically effective crosslink density distribution are
The concept of effective crosslinking density proposed by Scanlan is extended to heterogeneously crosslinking polymer. A kinetic-statistical model of effective crosslinking density of the gel is developed in free-radical heterogeneously crosslinking polymerization. The model is applied to the vinyl