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Nitrosation of Amides Involves a Pseudopericyclic 1,3-Sigmatropic Rearrangement

โœ Scribed by Birney, David M.


Book ID
120272889
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
79 KB
Volume
6
Category
Article
ISSN
1523-7060

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1-Aza-1โ€ฒ,3โ€ฒ-Diaza-3,3โ€ฒ-Sigmatropic Rearr
โœ M Teresa; V.L Carvalho; Ana M Lobo*; Paula S Branco; Sundaresan Prabhakar* ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 440 KB

l-Aryl-2-acyl-2-cyanohydrazine8 undergo smooth thermal rearrangements to provide 2aminoacylbenzimidazoles in excellentyields. A short synthesisof thehighlymutagenic dietary amine,IQ, is reported.@ 1997Elsevier ScienceLtd.