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Nitrones and oxaziridines. XXXI. Synthesis of some bicyclic 1-pyrroline 1-oxides

โœ Scribed by Black, DSC; Johnstone, LM


Book ID
121213786
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
1984
Tongue
English
Weight
631 KB
Volume
37
Category
Article
ISSN
0004-9425

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Synthesis and Reactivity of 1-Pyrroline-
โœ David StC. Black; Gavin L. Edwards; Richard H. Evans; Paul A. Keller; Sean M. La ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 151 KB

Some C5 mono-and diester-substituted 1-pyrroline-1-oxides have been prepared via reductive cyclisation of the corresponding g-nitro carbonyl compounds. Ethyl 2-phenyl-1-pyrroline-1-oxide-5-carboxylate 5c was regioselectively alkylated at C5. Acylation of this molecule occurs exclusively on the nitro