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Nitrolysis of urethanes derived from secondary alcohols as a new method for the synthesis of secondaryN-nitroamines

โœ Scribed by O. A. Luk'yanov; T. G. Mel'nikova; M. E. Shagaeva


Book ID
105601336
Publisher
Springer
Year
1998
Tongue
English
Weight
233 KB
Volume
47
Category
Article
ISSN
1573-9171

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A two-step and high-yield method for the synthesis of ฮฑ-thio aldehydes from aldehydes with one-carbon elongation is realized by using chloromethyl phenyl sulfoxide as a one-carbon homologating agent. The ฮฑ-thio aldehydes are easily converted to desulfurized alcohols with Bu 3 SnH and AIBN in refluxi