✦ LIBER ✦

Nitroglycal Concatenation: A Broadly Applicable and Efficient Approach to the Synthesis of Complex O-Glycans

✍ Scribed by Gottfried A. Winterfeld; Richard R. Schmidt

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 92 KB
Volume: 40
Category: Article
ISSN: 0044-8249
DOI: 10.1002/1521-3773(20010716)40:14<2654::aid-anie2654>3.0.co;2-l

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✦ Synopsis

Base-catalyzed glycosylations provide the basis for a new and general entry to the synthesis of mucin-type O-glycans. The desired α-linked 2-acetamidoglycosyl amino acids B are accessible selectively starting from glycals of type A. Fmoc=9-fluorenylmethoxycarbonyl.