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Nitrogenase Model Compounds: [μ-N2H2{Fe(“NHS4”)}2], the Prototype for the Coordination of Diazene to Iron Sulfur Centers and Its Stabilization through Strong NH ⃛ S Hydrogen Bonds

✍ Scribed by Prof. Dr. Dieter Sellmann; Dipl.-Chem. Wolfgang Soglowek; Dr. Falk Knoch; Dr. Matthias Moll


Publisher
John Wiley and Sons
Year
1989
Tongue
English
Weight
274 KB
Volume
28
Category
Article
ISSN
0044-8249

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✦ Synopsis


Syntex P2, diffractometer, room temperature, Mo,, radiation ( i = 71.069 pm). 20 5 5 0 ; 2088 unique reflections, 1935 with 1 2 2 u(I), empirical absorption correction, structure solution with Patterson methods. refinement with anisotropic temperature factors for all atoms except hydrogen, the CH bonds were calculated and not refined: 159 parameters, R = E(llF~ll -IF,II)/~lF,~ = 0.0643. Further details of the crystal structure investigation may be obtained from the Fachinformationszentrum Karlsruhe. Gesellschaft fur wissenschaftlich-technische Information mbH. D-7514 Eggenstein-Leopoldshafen 2 (FRG), o n quoting the depository number CSD-54021, the names of the authors, and the journal citation.