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Nitrogen mustards derived from diazaphosphole-2-oxide

โœ Scribed by Hans Zimmer; Arthur D. Sill


Book ID
104830603
Publisher
Springer
Year
1962
Tongue
English
Weight
149 KB
Volume
49
Category
Article
ISSN
0028-1042

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Cycloadducts from Diazocumulenes and 1,2
โœ Jochen Kerth; Gerhard Maas ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 462 KB ๐Ÿ‘ 1 views

Diazo-2-oxoalkyl)silanes 1 react with 2-acyl-1,2,3(ฮป 3 )-[3+2] cycloreversion into 2 and 4, and extrusion of molecular nitrogen. The latter process is likely to generate 3-diazaphospholes 4 to form [3+2] cycloaddition products 5, which indicate that 1-diazo-2-silyloxy-1-alkenes 2, alkenylidene-1,2,3