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Nitrogen inversion in n-substituted 2,2-bis(trifluoromethyl) aziridines

✍ Scribed by R.G. Kostyanovsky; I.I. Tchervin; A.A. Fomichov; Z.E. Samojlova; C.N. Makarov; Yu.V. Zeifman; B.L. Dyatkin


Book ID
104239929
Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
146 KB
Volume
10
Category
Article
ISSN
0040-4039

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## Abstract In the ^1^H NMR spectra of 2‐diethylaminomethyl‐3,4,6‐trichlorophenol (1) below 260 K, an additional splitting of the CH~2~ signal was found, which can be ascribed to the hindered nitrogen inversion. In the molecule of the __O__‐methylated derivative (2) this process is fast (on the NMR