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Nitrogen Inversion in Cyclic Amines and the Bicyclic Effect

✍ Scribed by Belostotskii, Anatoly M.; Gottlieb, Hugo E.; Shokhen, Michael

Book ID
126879558
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
214 KB
Volume
67
Category
Article
ISSN
0022-3263

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Barriers to inversion at nitrogen in bic
Barriers to inversion at nitrogen in bicyclic amines and hydrazines
✍ John W. Davies; John R. Malpass; Richard E. Moss πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 French βš– 244 KB

Nitrogen inversion barriers have been measured for 7-chloro-1,7-diazabicyclo-t2.2.11 heptane and 12.2.21octane; the unusual nature of the bridging nitrogen in bicycle [2.2.1) systems is discussed. The effects of ring strain and heteroatom substitution in raising the barrier to inversion are well kn