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Nitrogen heterocycles from trimethylbenzenes

✍ Scribed by Yu. V. Shklyaev; R. R. Ismagilov; Yu. S. Rozhkova; A. A. Fatykhov; I. B. Abdrakhmanov; A. G. Tolstikov; V. M. Dembitsky

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
100 KB
Volume
15
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

The reaction between 1,2,4‐trimethylbenzene 1, isobutyric aldehyde, and cyanoacetic ester afforded a mixture of three products: 3,3,5,6,8‐ pentamethyl‐1,2,3,4‐tetraisoquinolylidene‐1‐acetic acid ether (2) and its 3,3,5,6,7‐pentamethyl‐(3)‐ and 3,3,6,7,8‐pentamethyl‐1,2,3,4‐tetraisoquinolyli‐ dene‐1‐acetic acid ether isomers (3) in ratio 1:5:1. © 2004 Wiley Periodicals, Inc. Heteroatom Chem 15:471–476, 2004; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20045

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