Nitrogen-15 NMR study of the oxidation of the trisulfur trinitride anion by molecular oxygen: a comparison of the molecular and electronic structures of the S3N3-, S3N3O- and S3N3O2- ions
โ Scribed by Chivers, Tristram; Cordes, A. Wallace; Oakley, Richard T.; Pennington, William T.
- Book ID
- 126036724
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 841 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0020-1669
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๐ SIMILAR VOLUMES
Ab initio MO calculations (MP2/6-311 G\*\*//HF/6-311 G\*\*) have been performed for several isomers (including rotamers) of Me,S,O and Me,S,O,. MeS(0)SSMe exists as five ro- tamers; the most stable form (la) has a helical backbone CSSSC with S-S bond lengths of 206.0 (S"S") and 212.4 pm (S"S"'). The
than the C-O bond length of CH O in the gas phase by 0.044 A at the 3 MP2raug-cc-pVDZ level of theory. The structure of the CH S y moiety in
The barium perfluoroalkanedisulfonates Ba(O 3 S) 2 (CF 2 ) n (n = 1, 3ยฑ5) and the new potassium fluoroalkanedisulfonates K 2 (O 3 S) 2 CHF, K 2 (O 3 S) 2 CF 2 , and K 2 (O 3 S) 2 (CF 2 ) 5 have been prepared by reaction of (CF 2 ) n (SO 2 F) 2 (n = 1, 3ยฑ5) or CHF(SO 2 F) 2 with CaO (or Ca(OH) 2 ) an