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Nitrogen-15 chemical shifts for imidazole in aqueous cadmium(2+) solutions

โœ Scribed by Alei, Mohammed; Wageman, William E.; Morgan, Leon O.


Book ID
126406077
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
282 KB
Volume
17
Category
Article
ISSN
0020-1669

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15N NMR shifts for imidazole and 1-methy
โœ Mohammed Alei Jr.; William E Wageman ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 187 KB

The l5 N NMR frequencies for imidazole nitrogens undergo significant shifts when imidazole or l-methyl imidazole is taken from aqueous to CH2Cl2 solution. This shift is probably primarily due to strong hydrogen-bonding between 15N3 of imidazole and H20 protons in aqueous solution. It has been known