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Nitrobenzene hydrogenation: poisoning effect of tin dichloride on a platinum catalyst

✍ Scribed by Dermot J. Collins; Ronald P. Schneider Jr.; Mark C. Wolf; Burtron H. Davis


Publisher
Elsevier Science
Year
1990
Weight
259 KB
Volume
62
Category
Article
ISSN
0304-5102

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The mechanism of hydrogenation of alkynes catalyzed by the intermediates as cis-[H 2 Pt(PR 3 )(SnX 3 )(Οƒ-alkenyl)(acetone)], where the Οƒ-alkenyl ligand originates from an insertion [(PR 3 ) 2 PtHX]/SnX 2 system (PR 3 = PPh 3 , PMePh 2 ; X = Cl, Br) has been studied by means of parahydrogen-induced