Alkylation of remote non-activated δ-car
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Goran Petrović; Živorad Čeković
📂
Article
📅
1999
🏛
Elsevier Science
🌐
French
⚖ 940 KB
A free radical introduction of a functionalized alkyl chain onto remote non-activated 8-carbon atoms (Michael type alkylation) has been achieved Photolysis of suitable alkyl nitrites involves generation of 8-alkyl radicals and in the presence of radicophilic olefins, intermolecular addition takes pl