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Nitric Oxide and Carbon Monoxide Adsorption on Polycrystalline Iridium Electrodes: A Combined Raman and Infrared Spectroscopic Study

✍ Scribed by Zou, Shouzhong; Gómez, Roberto; Weaver, Michael J.


Book ID
127002620
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
421 KB
Volume
13
Category
Article
ISSN
0743-7463

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✍ Angeles Pulido; Petr Nachtigall; Montserrat Rodríguez Delgado; Carlos Otero Areá 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 550 KB

## Abstract **Bridged Ca**^**2+**^**⋅⋅⋅CO⋅⋅⋅Ca**^**2+**^ **complexes** are formed on dual‐cation sites, constituted by a pair of nearby Ca^2+^ cations, when CO is adsorbed on zeolite Ca‐A. Two types of such species can be formed, designated S2–S1 and S1–S1 (see picture). Ca^2+^⋅⋅⋅CO monocarbonyl sp