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Nitration of thiacalix[4]arene using nitrosium nitrate complexes: synthesis and characterization of tetranitro-, tetraamino-, and tetra(4-pyridylimino)tetrahydroxythiacalix[4]arene

✍ Scribed by Desroches, Cédric; Parola, Stéphane; Vocanson, Francis; Perrin, Monique; Lamartine, Roger; Létoffé, Jean-Marie; Bouix, Jean


Book ID
127344879
Publisher
Royal Society of Chemistry
Year
2002
Tongue
English
Weight
169 KB
Volume
26
Category
Article
ISSN
1144-0546

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The hetero-armedp-(tert -butyl)calix[4]arene 1 was synthesized by a stepwise procedure. This ligand presented a very strong complexing behavior towards Cu', giving the chiral complex 2 and parent species when reacted with Cu" salts. High-resolution NMR techniques were employed for the characterizati