This paper reports the dimerization of imidazdine nitroxides, containing alcohol groups in the second position, in frozen toluene. The parameters of dipole-dipole interaction of electron spins in dimers were determined using 2 mm EPR spectroscopy. A geometrical model for the dimers could be obtained
โฆ LIBER โฆ
Nitration of imidazoline-n-oxide nitroxides containing the aryl nitrone group
โ Scribed by L.B. Volodarsky; I.A. Grigor'ev; L.N. Grigor'eva; I.A. Kirilyuk
- Book ID
- 104234024
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 230 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
sitration of 4-aryl-3-imidazoline-3-oxide nitroxyl radicals leads to 4-nitroaryl-3-imidazoline-3-oxide nitroxides via oxammonium salts formation, the nitrone group being an ortho-para orientant.
3-Imidazoline nitroxyl radicals exceed all known radicals in stability to protic and Lewis acids '. This expands the pH range of media used for
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