Nickel(II) Thiolate Complexes with a Flexible cyclo-{Ni10S20} Framework
✍ Scribed by Chi Zhang; Satoshi Takada; Michael Kölzer; Tsuyoshi Matsumoto; Kazuyuki Tatsumi
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 548 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
The six-step synthesis of a chiral, pentadentate dihydrosalen ligand, carrying a mercaptomethyl group as additional binding site, is described. When this ligand was treated with nickel(I1) salts, a planar tetracoordinated nickel chelate was obtained, and not the expected pentacoordinated species. Th
The X-Ray structures of the 1:l copper(I1) complexes with racemic and optically active (+)-(R,R)-(2,6bis(pyrro1idin-2-y1)pyridine ((+)-bpp; (+)-I) were determined. Whereas the perchlorate 1 of the racemic complex contains the monomeric units with perfect C, symmetry, the sulfate of the optically act