Nickel(II) complexes of deprotonated thiourea; Crystal structure of Ni[(C6H5)NC(S)N{(C2H4)2O}]2

✍ Scribed by Chhaya Janakiram-Sayala; W. P. Bosman; J. Willemse; J. A. Cras

• Publisher: Elsevier Science
• Year: 2010
• Tongue: English
• Weight: 323 KB
• Volume: 99
• Category: Article
• ISSN: 0165-0513
• DOI: 10.1002/recl.19800991005

✦ Synopsis

Abstract

Nickel(II) complexes with deprotonated trisubstituted thiourea were prepared. The crystal structure of Ni[PhNC(S)N{(C~2~H~4~)~2~O}]~2~ showed that the nickel atom is centrosymmetrically square planar coordinated through the N and S of the thioureido ligands. The diamagnetic compound crystallizes in the monoclinic space group C2/c [a = 24.146(3), b = 10.480(2), c = 9.473(3) Å, β = 106.38(1)°] and contains four formula units per unit cell.