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Nickel(II)-catalyzed and acid-catalyzed acetohydroxamic acid formation from acetic acid

✍ Scribed by Munson, James W.; Connors, Kenneth A.

Book ID
127096456
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
716 KB
Volume
94
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Spectrophotometric determination of acid
Spectrophotometric determination of acid hydrazidesvianickel (II)-catalyzed hydroxamic acid formation
✍ James W. Munson; Kenneth A. Connors πŸ“‚ Article πŸ“… 1972 πŸ› John Wiley and Sons 🌐 English βš– 369 KB

The reaction of phenyl acetate with hydroxylamine to form acetohydroxamic acid is catalyzed by nickel (11). Kinetic studies revealed that of the two steps in this process (the first being formation of 0-acetylhydroxylamine and the second its conversion to acetohydroxamic acid), it is the second step

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✍ G. Bub; H.-U. HΓΆg πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 662 KB

In presence of the homogenous Rh/Cr/I catalyst system methyl formate can be isomerized to acetic acid under CO-pressure with high conversion rates and excellent selectivity. This catalyst system has never been applied before for this reaction.