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Nickel Complexes Based on Tridentate Pyrazolyl Ligands for Highly Efficient Dimerization of Ethylene to 1-Butene

✍ Scribed by Ajellal, Noureddine; Kuhn, Maria C. A.; Boff, Andressa D. G.; Hörner, Manfredo; Thomas, Christophe M.; Carpentier, Jean-François; Casagrande, Osvaldo L.


Book ID
120500458
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
92 KB
Volume
25
Category
Article
ISSN
0276-7333

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Highly selective nickel catalysts for et
✍ Lucilene L. de Oliveira; Roberta R. Campedelli; Maria C.A. Kuhn; Jean-François C 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 362 KB

A series of new nickel complexes NiCl 2 (L) based on tridentate NZN ligands (1, L = bis[2-(3,5dimethyl-pyrazolyl) has been prepared and characterized by elemental analysis. Upon activation with methylaluminoxane (MAO) or diethylaluminum chloride (DEAC), these new pre-catalysts show high activity in