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Nickel-Catalyzed Selective N-Arylation or N,N′-Diarylation of Secondary Diamines.

✍ Scribed by Eric Brenner; Raphael Schneider; Yves Fort


Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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ChemInform Abstract: Palladium-Catalyzed
✍ Christopher G. Frost; Paul Mendonca 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

Palladium-Catalyzed Mono-N-arylation of Enantiopure Diamines. -Hitherto unavailable enantiomerically pure N-aryl diamines, prepared using the title method, are investigated as chiral ligands in the asymmetric transfer hydrogenation of acetophenone. They are expected to become useful scaffolds for t