Nickel-Catalyzed Regio- and Stereoselective Reductive Coupling between Methylenecyclopropanes, Aldehydes, and Triethylborane with Retention of the Cyclopropane Ring
✍ Scribed by Dr. Kenichi Ogata; Daisuke Shimada; Prof. Dr. Shin-ichi Fukuzawa
- Book ID
- 112020162
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- English
- Weight
- 281 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
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## Abstract Transition‐metal‐catalyzed coupling of two different CC π components through a metallacycle intermediate is a highly atom economical method to construct CC bonds in organic synthesis. The metal‐catalyzed coupling of an alkene and alkyne generally gives an Alder‐ene or reductive coupli