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Nickel-catalyzed hydrodehalogenation of aryl halides

✍ Scribed by Weidauer, Maik; Irran, Elisabeth; Someya, Chika I.; Haberberger, Michael; Enthaler, Stephan


Book ID
120017530
Publisher
Elsevier Science
Year
2013
Tongue
English
Weight
819 KB
Volume
729
Category
Article
ISSN
0022-328X

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Pd/C-catalyzed room-temperature hydrodeh
✍ Pascal P Cellier; Jean-Francis Spindler; Marc Taillefer; Henri-Jean Cristau πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 234 KB

Treatment of aryl and heteroaryl halides with catalytic amounts of Pd/C in the presence of hydrazine hydrochloride in basic medium (sodium hydroxide or sodium t-butylate) at room temperature leads to the corresponding hydrodehalogenation products with high selectivity. Aryl iodides, bromides, chlori