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Nickel-catalyzed electrochemical homocoupling of alkenyl halides: rates and mechanisms

✍ Scribed by Céline Cannes; Eric Labbé; Muriel Durandetti; Marguerite Devaud; Jean Yves Nédélec


Book ID
103179877
Publisher
Elsevier
Year
1996
Tongue
English
Weight
769 KB
Volume
412
Category
Article
ISSN
1572-6657

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📜 SIMILAR VOLUMES


ChemInform Abstract: Nickel-Catalyzed El
✍ M. DURANDETTI; J. PERICHON; J.-Y. NEDELEC 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

## Nickel-Catalyzed Electrochemical Coupling of 2-and 3-Bromothiophene with Alkyl and Alkenyl Halides. -Bromothiophenes (I) and (IV) are efficiently coupled with reactive halides by a Ni(II)-catalyzed electrolysis using the sacrificial anode process. The products are interesting starting material

Nickel-catalysed electrochemical couplin
✍ Muriel Durandetti; Jacques Périchon; Jean-Yves Nédélec 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 190 KB

2-or 3-bromothiophene are efficiently coupled with activated alkyl chlorides (a-chloroesters, a-chloroketones, a-chloronitriles), benzyl chloride or vinyl halides, in a one step eleclxochemical reaction, using the sacrificial anode process and catalysis by NiBr2-2,2'-bipyridine (bipy).