Nickel-catalyzed cross-coupling of aryl phosphates with grignard and organoaluminium reagents. Synthesis of alkyl-, alkenyl-, and arylbenzenes from phenols

✍ Scribed by Tarnio Hayashi; Yoshio Katsuro; Yasuo Okamoto; Makoto Kumada

• Publisher: Elsevier Science
• Year: 1981
• Tongue: French
• Weight: 210 KB
• Volume: 22
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)82980-4

✦ Synopsis

Aryl phosphates derived from phenols were converted into alkyl-, alkenyl-, and arylbenzenes in high yields by cross-coupling with various kinds of Grignard and organoaluminium reagents in the presence of nickel(I1) catalysts.