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Nickel-catalyzed conjugate addition of zirconium alkenyls to .alpha.,.beta.-unsaturated ketones

✍ Scribed by Loots, Melanie J.; Schwartz, Jeffrey

Book ID
121681068
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
255 KB
Volume
99
Category
Article
ISSN
0002-7863

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Mechanistic aspects of the nickel-cataly
Mechanistic aspects of the nickel-catalyzed addition reaction of alkenyl-zirconium reagents to cyclopropyl ketones
✍ Melanie J. Loots; Fabian M. Dayrit; Jeffrey Schwartz πŸ“‚ Article πŸ“… 2010 πŸ› Wiley (John Wiley & Sons) βš– 428 KB πŸ‘ 1 views

## Abstract Nickel‐catalyzed addition of alkenylzirconium species to cyclopropyl ketones proceeds by an electron transfer mechanism. One‐electron reduction of the substrate leads to a ketyl which may either couple to give the 1, 2‐addition product or undergo a second one‐electron reduction, followe