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Nickel-Catalyzed C−O Activation of Phenol Derivatives with Potassium Heteroaryltrifluoroborates

✍ Scribed by Molander, Gary A.; Beaumard, Floriane


Book ID
118158716
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
259 KB
Volume
12
Category
Article
ISSN
1523-7060

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## Abstract The nickel‐catalyzed α‐arylation of ketones with readily available phenol derivatives (esters and carbamates) provides access to useful α‐arylketones. For this transformation, 3,4‐bis(dicyclohexylphosphino)thiophene (dcypt) was identified as a new, enabling, air‐stable ligand for this t